A molecular [Mn14] coordination cluster featuring two slowly relaxing nanomagnets

A molecular [Mn14] coordination cluster featuring two slowly relaxing nanomagnets.

An extended polypyrazolyl ligand has been used to assemble Mn ions into high spin entities, in the form of one stable molecule composed of two well defined clusters. The slow relaxation of the magnetisation observed is demonstrated to arise from each "half-SMM" composing this molecular cluster pair.

Nanomodulation of molecular nanomagnets.

Detailed synthetic, structural, and magnetic characterizations for a family of six [Mn(3)Zn(2)](13+) complexes are presented. These complexes have planar [Mn(3)(III)-(mu(3)-oxo)](7+) core magnetic units and have formulas represented by [cation](3)[Mn(3)Zn(2)(R-salox)(3)O(N(3))(6)X(2)], where [cation](+) = [NEt(4)](3)(+) or [AsPh(4)](3)(+); R = H or Me; and X = Cl(-), Br(-), I(-), or N(3)(-). Le...

Magnetic Anisotropy of Molecular Nanomagnets

Critical ruptures in a bundle of slowly relaxing fibers.

We study the damage enhanced creep rupture of disordered materials by means of a fiber bundle model. Broken fibers undergo a slow stress relaxation modeled by a Maxwell element whose stress exponent m can vary in a broad range. Under global load sharing we show that due to the strength disorder of fibers, the lifetime t(f) of the bundle has sample-to-sample fluctuations characterized by a log-n...

Molecular nanomagnets for information technologies †

Information storage by means of magnetic media is one of the oldest technologies for data recording, since the early prototype of magnetic wire recorder, the ‘‘telegraphone’’, was made by the Danish engineer Valdemar Paulsen in 1898. Magnetic media became very popular in the mid-1900s, with analog recording on audio and video tapes being developed; a milestone was the first digital device for m...